SQL JOIN allows us to “lookup” records on other table based on the given conditions between two tables. For example, if we have the department ID of each employee, then we can use this department ID of the employee table to join with the department ID of department table to lookup department names.
UNION operation allows us to add 2 similar data sets to create resulting data set that contains all the data from the source data sets. Union does not require any condition for joining. For example, if you have 2 employee tables with same structure, you can UNION them to create one result set that will contain all the employees from both of the tables.
SELECT * FROM EMP1 UNION SELECT * FROM EMP2;